Andalusite - Al2SiO5

Andalusite, named by Jean-Claude Delamétherie in 1798 for the supposed type locality, "Andalusia region" (Spain), is an aluminium mineral with the chemical formula Al2SiO5. Andalusite was first analysed by Werner on specimens coming from Spain. Both Werner and Delamétherie believed that the specimens came from Andalusia, which is why the latter named it "andalusite". However, it seems that the analyzed specimens came from El Cardoso (Guadalajara), a town they erroneously thought to be in Andalusia. Consequently the type locality must be considered El Cardoso, probably the outcrop located in Zahurdon. The error was perpetuated by other later authors, who considered that the origin was the province of Almeria, and remained so in the majority of books, even in modern ones.

Andalusite is a common regional metamorphic mineral which forms under low pressure and low to high temperatures. The minerals kyanite and sillimanite are polymorphs of andalusite, each occurring under different temperature-pressure regimes and are therefore rarely found together in the same rock. All three polymorphs can be used as index minerals in metamorphic rocks. They all develop in alumina-rich pelites under different conditions of temperature and pressure. Andalusite form al low pressures (<1.5 Kb) and low moderate temperature in thermal aureoles and regional metamorphism of Buchan type (high T and low P). At higher temperature its invert in sillimanite.

The variety chiastolite commonly contains dark inclusions of carbon or clay which form a checker-board pattern when shown in cross-section, while viridine, or manganandalusite, is a Mn-rich variety of andalusite, with deep green colors.

Optical properties

Color: Colourless or pale pink
Form: Usually occurs as elongate prisms with square cross section
Relief: Moderate
Cleavage: (001) good appearing as traces parallel to the prism edge in prismatic sections but intersecting at right angle in basal section
Interference colors: Low, first order (like quartz)
Alteration: Commonly in sercite
al2sio5.png

Al2SiO5 phase diagram



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Andalusite porphyroblasts. Clooney, Donegal. Keele collection. From G. Stimpson.




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Andalusite (chiastolite). From Wikipedia.




Bibliography



• Bucher, K., & Grapes, R. (2011). Petrogenesis of metamorphic rocks. Springer Science & Business Media.
• Fossen, H. (2016). Structural geology. Cambridge University Press.
• Howie, R. A., Zussman, J., & Deer, W. (1992). An introduction to the rock-forming minerals (p. 696). Longman.
• Passchier, Cees W., Trouw, Rudolph A. J: Microtectonics (2005).
• Philpotts, A., & Ague, J. (2009). Principles of igneous and metamorphic petrology. Cambridge University Press.
• Shelley, D. (1993). Igneous and metamorphic rocks under the microscope: classification, textures, microstructures and mineral preferred-orientations.
• Vernon, R. H. & Clarke, G. L. (2008): Principles of Metamorphic Petrology. Cambridge University Press.
• Vernon, R. H. (2018). A practical guide to rock microstructure. Cambridge university press.


Photo
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Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
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Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
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Garnet and andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
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Garnet (isotropic) and andalusite crystals (I order gray, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
andalusite2016(6).jpg

Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
andalusite2016(5).jpg

Andalusite crystals (I order gray, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
andalusite2016(9).jpg

Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
andalusite2016(10).jpg

Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
andalusite2016(11).jpg

Garnet surrounded by andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 2x (Field of view = 7mm)
andalusite2016(12).jpg

Garnet surrounded by andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
andalusite2016(13).jpg

Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
andalusite2016(14).jpg

Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
andalusite2016(15).jpg

Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
andalusite2016(16).jpg

Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
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Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
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Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
andalusite2016(19).jpg

Andalusite crystal (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
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Andalusite crystal (with numerous inclusions). XPL image, 2x (Field of view = 7mm)
andalusite2016(21).jpg

Andalusite crystal (I order gray, with numerous inclusions). XPL (with Compensator plate) image, 2x (Field of view = 7mm)
andalusite2016(22).jpg

Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
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Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
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Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
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Andalusite crystals (I order gray, with numerous inclusions). XPL image, 2x (Field of view = 7mm)
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Andalusite crystals (beige/pale pink, with numerous inclusions). PPL image, 10x (Field of view = 2mm)
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Irregular, high relief Andalusite crystals in a Hornfels. PPL image, 10x (Field of view = 2mm)
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Irregular (I order gray) Andalusite crystals in a Hornfels. PPL image, 10x (Field of view = 2mm)
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Irregular, high relief Andalusite crystals in a Hornfels. PPL image, 10x (Field of view = 2mm)
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Andalusite crystal surrounded by Biotite in a schist. Paleozoic basement, Capo Calamita, Elba island (Italy). PPL image, 10x (Field of view = 2mm)
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Andalusite crystal surrounded by Biotite in a schist. Paleozoic basement, Capo Calamita, Elba island (Italy). XPL image, 10x (Field of view = 2mm)
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Andalusite crystals (Gray) in a schist. Paleozoic basement, Capo Calamita, Elba island (Italy). XPL image, 10x (Field of view = 2mm)
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Andalusite crystals (Gray) in a schist. Paleozoic basement, Capo Calamita, Elba island (Italy). XPL image, 2x (Field of view = 7mm)
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Andalusite crystals (Gray) in a schist. Paleozoic basement, Capo Calamita, Elba island (Italy). XPL image, 2x (Field of view = 7mm)
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Andalusite crystals (Gray) in a schist. Paleozoic basement, Capo Calamita, Elba island (Italy). XPL image, 10x (Field of view = 2mm)
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Andalusite crystals in a gneiss. PPL image, 2x (Field of view = 7mm)
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Andalusite crystals with biotite inclusions in a gneiss. XPL image, 2x (Field of view = 7mm)
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Garnet encircled by Andalusite crystals. PPL image, 2x (Field of view = 7mm)
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Garnet (isotropic) encircled by Andalusite crystals (gray). XPL image, 2x (Field of view = 7mm)
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Andalusite and biotite crystals. PPL image, 2x (Field of view = 7mm)
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Andalusite and biotite crystals. PPL image, 10x (Field of view = 2mm)
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Andalusite and biotite crystals. PPL image, 2x (Field of view = 7mm)
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Andalusite (gray) and biotite crystals. XPL image, 2x (Field of view = 7mm)
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Andalusite (gray), quartz and biotite crystals. XPL image, 2x (Field of view = 7mm)
andalusite2015(12).jpg

Andalusite crystals with biotite inclusions in a gneiss. XPL image, 2x (Field of view = 7mm)
andalusite2015(13).jpg

Andalusite and biotite crystals. PPL image, 2x (Field of view = 7mm)
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Andalusite and biotite crystals. XPL image, 2x (Field of view = 7mm)
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Andalusite and biotite crystals. PPL image, 10x (Field of view = 2mm)
andalusite2015(16).jpg

Andalusite (gray) and biotite crystals. XPL image, 10x (Field of view = 2mm)
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Andalusite, garnet and biotite crystals. PPL image, 2x (Field of view = 7mm)
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Andalusite (gray), garnet and biotite crystals. XPL image, 2x (Field of view = 7mm)
andalusite2015(21).jpg

Andalusite and biotite crystals. PPL image, 10x (Field of view = 2mm)
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Andalusite and biotite crystals. XPL image, 10x (Field of view = 2mm)
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Andalusite crystal (lower part of the photo) associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. PPL image, 2x (Field of view = 7mm)
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Andalusite crystal (lower part of the photo, I order gray) associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. XPL image, 2x (Field of view = 7mm)
andalusite(elba)(4).jpg

Andalusite crystal with green spinel corona. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. PPL image, 2x (Field of view = 7mm)
andalusite(elba)(5).jpg

Andalusite crystal associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. PPL image, 10x (Field of view = 2mm)
andalusite(elba)(6).jpg

Andalusite crystal associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. PPL image, 10x (Field of view = 2mm)
andalusite(elba)(7).jpg

Andalusite crystal associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. XPL image, 10x (Field of view = 2mm)
andalusite(elba)(9).jpg

Andalusite crystal (pale pink) associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. PPL image, 2x (Field of view = 7mm)
andalusite(elba)(8).jpg

Andalusite crystal (pale pink) associated with biotite. MME (Mafic microgranular enclaves) in the S.Andrea granite. Elba Island, Italy. PPL image, 10x (Field of view = 2mm)